Published

2008-05-01

Separating a water-propanol mixture using PDMS pervaporation membranes

Separación de mezclas agua-propanol usando membranas de preevaporación PDMS

DOI:

https://doi.org/10.15446/ing.investig.v28n2.14892

Keywords:

pervaporation, organic solvent, PDMS membrane, dehydration, water/propanol mixture (en)
pervaporation, membrane en PDMS, solvants organiques, eau /propanol, déshydratation (es)

Authors

  • Mahacine Amrani .

Recovering and purifying organic solvents during chemical and pharmaceutical synthesis has great economic and environmental importance. Water-alcohol mixture pervaporation was investigated using a pervaporation cell and hydrophobic membranes. This work studied polydimethylsiloxane (PDMS) membrane performance and hydrophobic membranes for removing propanol from aqueous mixtures. PDMS is recognised as being alcohol permselective during pervaporation. It was also observed that water was transferred through a hydrophobic membrane as water’s molecular size is smaller than that of propanol. A laboratory-scale pervaporation unit was used for studying this membrane’s separation characteristic in terms of pervaporation flux and selectivity for feeds containing up to water mass and 30°C-50°C. Total propanol/water flux was observed to vary as operating temperature increased. Although PDMS membranes presented good characteristics for separating water/propanol mixtures, the separation factor and pervaporation flow decreased as water content in the feed increased. The tested membrane was found to be very efficient for water concentrations of less than 0.3, corresponding to total flux transfer maximum.

La recuperación y purificación de disolventes orgánicos en la química farmacéutica resulta de gran importancia para la economía y el medio ambiente. La separación de mezclas de agua/alcohol por el proceso de pervaporación se llevó a cabo a través de membranas hidrofóbicas. En este trabajo se estudia el rendimiento de las membranas de polidimetilsiloxano (PDMS) para la deshidratación de mezclas agua/propanol por el proceso de preevaporación. El PDMS es reconocido por su selectividad de permeabilidad al alcohol preferentemente en mezclas de agua/alcohol durante el preevaporación debido a su tamaño molecular, aunque aún se presente penetración de agua a través de la membrana hidrofóbica. Se utilizó una unidad de preevaporación a escala de laboratorio para el estudio de esta membrana de separación evaluando características en términos de pervaporación como el flujo y la selectividad de los canales con un contenido máximo de masa de agua y de 30 °C a 50 °C. El flujo de propanol/agua fue observado al variar la temperatura. A pesar que el PDMS presentó buenas características para la separación de mezclas de agua/propanol, el factor de separación y el flujo de pervaporación disminuyen a medida que el contenido de agua en la carga aumenta. La membrana PDMS resultó ser muy eficiente para concentraciones de a gua de menos de 0.3, lo que corresponde al total del flujo de transferencia máxima.

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How to Cite

APA

Amrani, M. (2008). Separating a water-propanol mixture using PDMS pervaporation membranes. Ingeniería e Investigación, 28(2), 53–58. https://doi.org/10.15446/ing.investig.v28n2.14892

ACM

[1]
Amrani, M. 2008. Separating a water-propanol mixture using PDMS pervaporation membranes. Ingeniería e Investigación. 28, 2 (May 2008), 53–58. DOI:https://doi.org/10.15446/ing.investig.v28n2.14892.

ACS

(1)
Amrani, M. Separating a water-propanol mixture using PDMS pervaporation membranes. Ing. Inv. 2008, 28, 53-58.

ABNT

AMRANI, M. Separating a water-propanol mixture using PDMS pervaporation membranes. Ingeniería e Investigación, [S. l.], v. 28, n. 2, p. 53–58, 2008. DOI: 10.15446/ing.investig.v28n2.14892. Disponível em: https://revistas.unal.edu.co/index.php/ingeinv/article/view/14892. Acesso em: 28 mar. 2024.

Chicago

Amrani, Mahacine. 2008. “Separating a water-propanol mixture using PDMS pervaporation membranes”. Ingeniería E Investigación 28 (2):53-58. https://doi.org/10.15446/ing.investig.v28n2.14892.

Harvard

Amrani, M. (2008) “Separating a water-propanol mixture using PDMS pervaporation membranes”, Ingeniería e Investigación, 28(2), pp. 53–58. doi: 10.15446/ing.investig.v28n2.14892.

IEEE

[1]
M. Amrani, “Separating a water-propanol mixture using PDMS pervaporation membranes”, Ing. Inv., vol. 28, no. 2, pp. 53–58, May 2008.

MLA

Amrani, M. “Separating a water-propanol mixture using PDMS pervaporation membranes”. Ingeniería e Investigación, vol. 28, no. 2, May 2008, pp. 53-58, doi:10.15446/ing.investig.v28n2.14892.

Turabian

Amrani, Mahacine. “Separating a water-propanol mixture using PDMS pervaporation membranes”. Ingeniería e Investigación 28, no. 2 (May 1, 2008): 53–58. Accessed March 28, 2024. https://revistas.unal.edu.co/index.php/ingeinv/article/view/14892.

Vancouver

1.
Amrani M. Separating a water-propanol mixture using PDMS pervaporation membranes. Ing. Inv. [Internet]. 2008 May 1 [cited 2024 Mar. 28];28(2):53-8. Available from: https://revistas.unal.edu.co/index.php/ingeinv/article/view/14892

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